Kinetic-Spectrophotometric Determination of Trace Amounts of Silver Using the Oxidation of Thionine with Peroxodisulfate

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Kinetic-spectrophotometric determination of trace amounts of silver using the oxidation of thionine with peroxodisulfate.

A simple, rapid and sensitive method has been developed for determination of traces of silver(I) (0.2 - 13 ng mL(-1)) based on its catalytic effect on the oxidation of thionine by peroxodisulfate in the presence of 1 - 10 phenanthroline as an activator. The reaction is monitored spectrophotometrically by measuring the decrease in absorbance of thionine at 600 nm by the fixed time method. The de...

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A simple, sensitive and rapid method for determination of trace amounts of nitrite ion in real samples is reported. The reaction is initiated by adding known volumes of a nitrite ion solution of identified concentration to acidic solutions of thionine which causes decolorizaiton of reagent with time. The absorbance changes is then monitored spectrophotometrically at l...

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ژورنال

عنوان ژورنال: Analytical Sciences

سال: 2006

ISSN: 0910-6340,1348-2246

DOI: 10.2116/analsci.22.1601